The Fluctuation Theorem is a fundamental result in nonequilibrium statistical mechanics that describes the probability of observing fluctuations in the entropy production of a system far from equilibrium. It states that the probability of observing a certain amount of entropy production over a given time is related to the probability of observing a negative amount of entropy production, . Mathematically, this can be expressed as:
where and are the probabilities of observing the respective entropy productions, and is the Boltzmann constant. This theorem highlights the asymmetry in the entropy production process and shows that while fluctuations can lead to temporary decreases in entropy, such occurrences are statistically rare. The Fluctuation Theorem is crucial for understanding the thermodynamic behavior of small systems, where classical thermodynamics may fail to apply.
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