The perovskite structure refers to a specific type of crystal structure that is characterized by the general formula , where and are cations of different sizes, and is an anion, typically oxygen. This structure is named after the mineral perovskite (calcium titanium oxide, ), which was first discovered in the Ural Mountains of Russia.
In the perovskite lattice, the larger cations are located at the corners of a cube, while the smaller cations occupy the center of the cube. The anions are positioned at the face centers of the cube, creating a three-dimensional framework that can accommodate a variety of different ions, thus enabling a wide range of chemical compositions and properties. The unique structural flexibility of perovskites contributes to their diverse applications, particularly in areas such as solar cells, ferroelectrics, and superconductors.
Moreover, the ability to tune the properties of perovskite materials through compositional changes enhances their potential in optoelectronic devices and energy storage technologies.
Start your personalized study experience with acemate today. Sign up for free and find summaries and mock exams for your university.